South and Southeast Asia controls black carbon characteristics of Meili Snow Mountains in southeast Tibetan Plateau.

South and Southeast Asia (SSA) emitted black carbon (BC) exerts potential effects on glacier and snow melting and regional climate change in the Tibetan Plateau. In this study, online BC measurements were conducted for 1 year at a remote village located at the terminus of the Mingyong Glacier below the Meili Snow Mountains. The Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) was used to investigate the contribution and potential effect of SSA-emitted BC. In addition, variations in the light absorption characteristics of BC and brown carbon (BrC) were examined. The results indicated that the annual mean concentration of BC was 415 ± 372 ngm-3, with the highest concentration observed in April (monthly mean: 930 ± 484 ngm-3). BC exhibited a similar diurnal variation throughout the year, with two peaks observed in the morning (from 8:00 to 9:00 AM) and in the afternoon (from 4:00 to 5:00 PM), with even lower values at nighttime. At a short wavelength of 370 nm, the absorption coefficient (babs) reached its maximum value, and the majority of babs values were < 20 Mm-1, indicating that the atmosphere was not overloaded with BC. At the same wavelength, BrC substantially contributed to babs, with an annual mean of 25.2 % ± 12.8 %. SSA was the largest contributor of BC (annual mean: 51.1 %) in the study area, particularly in spring (65.6 %). However, its contributions reached 20.2 % in summer, indicating non-negligible emissions from activities in other regions. In the atmosphere, the SSA BC-induced radiative forcing (RF) over the study region was positive. While at the near surface, the RF exhibited a significant seasonal variation, with the larger RF values occurring in winter and spring. Overall, our findings highlight the importance of controlling BC emissions from SSA to protect the Tibetan Plateau against pollution-related glacier and snow cover melting.

Weak transport of atmospheric water-insoluble particulate carbon from South Asia to the inner Tibetan Plateau in the monsoon season.

Carbonaceous particles play a crucial role in atmospheric radiative forcing. However, our understanding of the behavior and sources of carbonaceous particles in remote regions remains limited. The Tibetan Plateau (TP) is a typical remote region that receives long-range transport of carbonaceous particles from severely polluted areas such as South Asia. Based on carbon isotopic compositions (Δ14C/δ13C) of water-insoluble particulate carbon (IPC) in total suspended particle (TSP), PM2.5, and precipitation samples collected during 2020-22 at the Nam Co Station, a remote site in the inner TP, the following results were achieved: First, fossil fuel contributions (ffossil) to IPC in TSP samples (28.60 ± 9.52 %) were higher than that of precipitation samples (23.11 ± 8.60 %), and it is estimated that the scavenging ratio of IPC from non-fossil fuel sources was around 2 times that from fossil fuel combustion during the monsoon season. The ffossil of IPC in both TSP and PM2.5 samples peaked during the monsoon season. Because heavy precipitation during the monsoon season scavenges large amounts of long-range transported carbonaceous particles, the contribution of local emissions from the TP largely outweighs that from South Asia during this season. The results of the IPC source apportionment based on Δ14C and δ13C in PM2.5 samples showed that the highest contribution of liquid fossil fuel combustion also occurred in the monsoon season, reflecting increased human activities (e.g., tourism) on the TP during this period. The results of this study highlight the longer lifetime of fossil fuel-sourced IPC in the atmosphere than that of non-fossil fuel sources in the inner TP and the importance of local emissions from the TP during the monsoon season. The findings provide new knowledge for model improvement and mitigation of carbonaceous particles.

Insights on aerosol properties using two decades-long ground-based remote sensing datasets in Moldova, Eastern Europe.

Aerosol optical properties were studied over Chisinau in Moldova, one of the longest running AERONET sites in Eastern Europe. During two decades (September 1999-November 2018), the mean aerosol optical depth (AOD) and Angstrom exponent (AE) were observed as 0.21 ± 0.13 and 1.49 ± 0.29, respectively. The highest AOD (0.24 ± 0.13) and AE (1.60 ± 0.26) were observed during the summer. More than half (∼55%) of the share was occupied by clean continental aerosols with seasonal order of winter (74.8%) > autumn (62%) > spring (48.9%) > summer (44.8%) followed by mixed aerosols with a respective contribution of 30.7% (summer), 28.4% (spring), 22.5 (autumn) and 16.4% (winter). A clear dominance of volume size distribution in the fine mode indicated the stronger influence of anthropogenic activities resulting in fine aerosol load in the atmosphere. The peak in the fine mode was centered at 0.15 µm, whereas that of the coarse mode was centered either at 3.86 µm (summer and autumn) or 5.06 µm (spring and winter). 'Extreme' aerosol events were observed during 21 days with a mean AOD (AE) of 0.99 ± 0.32 (1.43 ± 0.43), whereas 'strong' events were observed during 123 days with a mean AOD (AE) of 0.57 ± 0.07 (1.44 ± 0.40), mainly influenced by anthropogenic aerosols (during 19 and 101 days of each event type) from urban/industrial and biomass burning indicated by high AE and fine mode fraction. During the whole period (excluding events days), the fine and coarse mode peaks were observed at the radius of 0.15 and 5.06 µm, which in the case of extreme (strong) events were at 0.19 (0.15) and 3.86 (2.24) µm respectively. The fine mode volume concentration was 4.78 and 3.32 times higher, whereas the coarse mode volume concentration was higher by a factor of 1.98 and 2.27 during extreme and strong events compared to the whole period.

Characterization of columnar aerosol over a background site in Central Asia.

Ground-based observational characterization of atmosphere aerosols over Central Asia is very limited. This study investigated the columnar aerosol characteristics over Issyk-Kul, Kyrgyzstan, a background site in Central Asia using the long-term (∼14 years: August 2007-November 2021) data acquired with the Cimel sunphotometer. The mean aerosol optical depth (AOD) and Ångström exponent (AE) during the observation period were 0.14 ± 0.10 and 1.19 ± 0.41, respectively. Both AOD and AE varied across seasons, with highest AOD in spring (0.17 ± 0.17). Regarding the aerosol types, clean continental aerosols were dominant type (65%), followed by mixed aerosols (∼19%), clean marine aerosols (∼14%), dust (0.8%), and urban/industrial and biomass burning aerosol (0.7%). The aerosol volume size distribution was bimodal indicating the influence of both anthropogenic and natural aerosols with clear dominance of coarse mode during the spring season. Mainly dust and mixed aerosols were present during high aerosol episodes while the coarse mode aerosol volume concentration was 7.5 (strong episodes) and ∼19 (extreme episodes) times higher than the whole period average. Aerosol over this background sites were from local and regional sources with some contribution of long-range transport.

South Asian black carbon is threatening the water sustainability of the Asian Water Tower.

Long-range transport of black carbon from South Asia to the Tibetan plateau and its deposition on glaciers directly enhances glacier melt. Here we find South Asian black carbon also has an indirect effect on the plateau's glaciers shrinkage by acting to reduce the water supply over the southern Tibetan plateau. Black carbon enhances vertical convection and cloud condensation, which results in water vapor depletion over the Indian subcontinent that is the main moisture flux source for the southern Tibetan plateau. Increasing concentrations of black carbon causes a decrease in summer precipitation over the southern Tibetan plateau, resulting in 11.0% glacier deficit mass balance on average from 2007 to 2016; this loss rises to 22.1% in the Himalayas. The direct (accelerated melt) and indirect (mass supply decrease) effects of black carbon are driving the glacial mass decline of the so-called "Asian Water Tower".

Coupling of decreased snow accumulation and increased light-absorbing particles accelerates glacier retreat in the Tibetan Plateau.

Most glaciers in the Tibetan Plateau (TP) are experiencing dramatic retreat, which is resulting in serious environmental and ecological consequences. In addition to temperature increases, increased light-absorbing particles (LAPs) and decreased precipitation were proposed to, independently, play important roles in reducing glacier accumulation. Based on investigations of effect from an extremely low precipitation event in the TP and surrounding regions caused by La Niña from October 2020 to April 2021, a new mechanism was provided. It was shown that decreased precipitation during study period leaded to both low snow accumulation and high LAP concentrations in snow on glacier surfaces in the TP. This phenomenon will strongly enhance earlier and accelerated glacier melt in this critical region and needs to be considered in future related studies.

Atmospheric particle-bound polycyclic aromatic compounds over two distinct sites in Pakistan: Characteristics, sources and health risk assessment.

Much attention is drawn to polycyclic aromatic hydrocarbons (PAHs) as an air pollutant due to their toxic, mutagenic and carcinogenic properties. Therefore, to understand the levels, seasonality, sources and potential health risk of PAHs in two distinct geographical locations at Karachi and Mardan in Pakistan, total suspended particle (TSP) samples were collected for over one year period. The average total PAH concentrations were 31.5 ± 24.4 and 199 ± 229 ng/m3 in Karachi and Mardan, respectively. The significantly lower concentration in Karachi was attributed to diffusion and dilution of the PAHs by the influence of clean air mass from the Arabian sea and high temperature, enhancing the volatilization of the particle phase PAHs to the gas phase. Conversely, the higher concentration (~6 times) in Mardan was due to large influence from local and regional emission sources. A clear seasonality was observed at both the sites, with the higher values in winter and post-monsoon due to higher emissions and less scavenging, and lower values during monsoon season due to the dilution effect. Diagnostic ratios and principal component analysis indicated that PAHs in both sites originated from traffic and mixed combustion sources (fossil fuels and biomass). The average total BaP equivalent concentrations (BaPeq) in Karachi and Mardan were 3.26 and 34 ng/m3, respectively, which were much higher than the WHO guideline of 1 ng/m3. The average estimates of incremental lifetime cancer risk from exposure to airborne BaPeq via inhalation indicated a risk to human health from atmospheric PAHs at both sites.

Black Carbon in Surface Soil and Its Sources in Three Central Asian Countries.

Black carbon (BC) aerosol impacts the air quality, public health, agricultural productivity, weather, monsoon, cryosphere, and climate system from the local to the global scale. However, its distribution over vast Central Asia is poorly known, because it is one of the poorly sampled regions of the world. BC in the soil can be resuspended into the atmosphere and transported to downwind regions with sensitive ecosystems and vulnerable populations, such as from Central Asian countries to the cryospheric regions in the Tianshan Mountain and the Tibetan Plateau, which could accelerate the melting of the snowfields and glaciers. We report the distribution of BC and total organic carbon (TOC) in surface soil with samples collected at multiple sites, for the first time, over three countries in Central Asia (Uzbekistan, Tajikistan, and Kyrgyzstan). The mean BC (TOC) concentrations over three countries were 0.06 ± 0.06 (11.86 ± 4.84) mg g-1, 0.15 ± 0.21 (20.35 ± 10.96) mg g-1, and 0.32 ± 0.29 (26.45 ± 20.38) mg g-1, respectively. They were found to be originated from the same or similar sources, at least over Tajikistan and Kyrgyzstan, as indicated by their high and significant correlation (R2 > 0.6, p < 0.001). The char/soot ratio indicated the diesel and gasoline combustion as dominant BC sources over this region. To gain further insights into the soil BC and its implications to air quality, climate, and cryosphere, future studies should include a wider area over Central Asia with different land-use types and other soil parameters combined with atmospheric simulations for this important yet relatively less studied region of the world.

Black carbon concentration in the central Himalayas: Impact on glacier melt and potential source contribution.

This study discusses year-long (October 2016-September 2017) observations of atmospheric black carbon (BC) mass concentration, its source and sector contributions using a chemical transport model at a high-altitude (28°12'49.21″N, 85°36'33.77″E, 4900 masl) site located near the Yala Glacier in the central Himalayas, Nepal. During a field campaign, fresh snow samples were collected from the surface of the Yala Glacier in May 2017, which were analysed for BC and water-insoluble organic carbon mass concentration in order to estimate the scavenging ratio and surface albedo reduction. The maximum BC mass concentration in the ambient atmosphere (0.73 µg m-3) was recorded in the pre-monsoon season. The BC and water-insoluble organic carbon analysed from the snow samples were in the range of 96-542 ng g-1 and 152-827 ng g-1, respectively. The source apportionment study using the absorption Ångström exponent from in situ observations indicated approximately 44% contribution of BC from biomass-burning sources and the remainder from fossil-fuel sources during the entire study period. The source contribution study, using model data sets, indicated ∼14% contribution of BC from open-burning and ∼77% from anthropogenic sources during the study period. Our analysis of regional contributions of BC indicated that the highest contribution was from both Nepal and India combined, followed by China, while the rest was distributed among the nearby countries. The surface snow albedo reduction, estimated by an online model - Snow, Ice, and Aerosol Radiation - was in the range of 0.8-3.8% during the pre-monsoon season. The glacier mass balance analysis suggested that BC contributed to approximately 39% of the total mass loss in the pre-monsoon season.

Spatio-temporal characteristics of air pollutants over Xinjiang, northwestern China.

To understand the characteristics of particulate matter (PM) and other air pollutants in Xinjiang, a region with one of the largest sand-shifting deserts in the world and significant natural dust emissions, the concentrations of six air pollutants monitored in 16 cities were analyzed for the period January 2013-June 2019. The annual mean PM2.5, PM10, SO2, NO2, CO, and O3 concentrations ranged from 51.44 to 59.54 µg m-3, 128.43-155.28 µg m-3, 10.99-17.99 µg m-3, 26.27-31.71 µg m-3, 1.04-1.32 mg m-3, and 55.27-65.26 µg m-3, respectively. The highest PM concentrations were recorded in cities surrounding the Taklimakan Desert during the spring season and caused by higher amounts of wind-blown dust from the desert. Coarse PM (PM10-2.5) was predominant, particularly during the spring and summer seasons. The highest PM2.5/PM10 ratio was recorded in most cities during the winter months, indicating the influence of anthropogenic emissions in winters. The annual mean PM2.5 (PM10) concentrations in the study area exceeded the annual mean guidelines recommended by the World Health Organization (WHO) by a factor of ca. ∼5-6 (∼7-8). Very high ambient PM concentrations were recorded during March 19-22, 2019, that gradually influenced the air quality across four different cities, with daily mean PM2.5 (PM10) concentrations ∼8-54 (∼26-115) times higher than the WHO guidelines for daily mean concentrations, and the daily mean coarse PM concentration reaching 4.4 mg m-3. Such high PM2.5 and PM10 concentrations pose a significant risk to public health. These findings call for the formulation of various policies and action plans, including controlling the land degradation and desertification and reducing the concentrations of PM and other air pollutants in the region.

Black carbon and mercury in the surface sediments of Selin Co, central Tibetan Plateau: Covariation with total carbon.

Tibetan Plateau (TP) is an important geographical region for investigating the long-range transport of pollutants as limited emission sources exist in this region. In this study, based on analysis of 61 surface samples, we report the spatial distribution and concentrations of BC, Hg, total organic carbon (TOC) and inorganic carbon (IC) in surface sediments of Selin Co, the largest lake in central Tibet. The mean BC and Hg concentrations were 0.62 ± 0.34 mg/g and 32.03 ± 9.88 ng/g (range: 0.03-1.47 mg/g and 13.83-51.81 ng/g respectively), which were lower than the values from other lakes in the Himalayan-Tibetan Plateau (HTP). BC and Hg exhibited similar spatial distribution in the surface sediments. Similarly, the mean TOC and IC were 2.19 ± 1.46% and 3.13 ± 1.07% (range: 0.0007-7.78% and 0.30-5.30% respectively). BC/TOC ratio, as well as char/soot ratio, suggests biomass burning as a major source of BC in the sediments via the influence of long-range transport. The positive correlation between the concentrations of BC and Hg suggests similar emission sources or transport pathway. Concentrations of BC and Hg were higher in fine grain particles (size <~50 µm) which were capable of transport and deposit in the deeper part of the lake, as suggested by a significant relationship between water depth and particle size. This study elucidates the extent of pollution in very recent ages and also could serve as the basis for paleo-environmental studies in future.